[Ag(NH3)2]++2H+=Ag++2NH4+
K=[Ag+]× [NH4+]^2 ÷ { [Ag(NH3)2+ ]× [H+]^2}
=[Ag+]×[NH4+]^2× [OH]^2 / { [Ag(NH3)2+ ]×[H+]^2× [OH-]^2}
=[Ag+]×[NH4+]^2× [OH]^2 /{[Ag(NH3)2+ ] × Kw^2 }
=[NH4+]^2× [OH]^2/{ [Ag(NH3)2+ ] ÷[Ag+] × Kw^2}
=[NH4+]^2× [OH]^2÷ [NH3]^2/{ [Ag(NH3)2+ ] ÷[Ag+] ÷ [NH3]^2 × Kw^2}
=KbNH3^2 /{K穩(wěn)× Kw^2}
=(1.77*10^-5）)^2 /{10^7.40*10^-28}
=1.25*10^11
K很大,說明基本完全反應(yīng)
[Ag(NH3)2]++2H+=Ag++2NH4+
0.2V0.6V00
0 0.2V 0.2V 0.4V
因此溶液中[H+]=0.2V/2V=0.1mol/L
[Ag+]=0.2V/2V=0.1mol/L
[NH4+]=0.4V/2V=0.2mol/L
K很大,說明基本完全反應(yīng),溶液中[Ag(NH3)2]＋濃度很小,可以認(rèn)為[H+]、[Ag+]、[NH4+]基本不變
設(shè)[Ag(NH3)2]＋為x
[Ag(NH3)2]++2H+=Ag++2NH4+
x 0.10.1 0.2
K =[Ag+]× [NH4+]^2 ÷ { [Ag(NH3)2+ ]× [H+]^2}
= 0.1× (0.2)^2 ÷ { x ×(0.1)^2}= 1.25*10^11
x=3.2*10^-12mol/L
即[Ag(NH3)2]＋的濃度=3.2*10^-12mol/L