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  • A system of propane and n-butane exists in two-phase vapor/liquid equilibrium at 10.0

    A system of propane and n-butane exists in two-phase vapor/liquid equilibrium at 10.0
    bar and 323 K.The mole fraction of propane is about 0.67 in the vapor phase and about
    0.40 in the liquid phase.Additional pure propane is added to the system,which is brought
    again to equilibrium at the same T and P,with both liquid and vapor phases still present.
    What is the effect of the addition of propane on the mole fractions of propane in the
    vapor and liquid phases?
    英語人氣:874 ℃時(shí)間:2020-02-03 11:34:32
    優(yōu)質(zhì)解答
    這一題考查的是“杠桿原理(lever rule)”.從二元?dú)庖浩胶庀鄨D上可以看出來,加入純丙烷后,在同溫同壓下達(dá)到新的相平衡,此時(shí)丙烷在氣相中的摩爾分?jǐn)?shù)仍然是0.67,在液相中的摩爾分?jǐn)?shù)仍然是0.40.設(shè)加入純丙烷以前,體系...
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